Please use this identifier to cite or link to this item: https://gnanaganga.inflibnet.ac.in:8443/jspui/handle/123456789/15097
Title: Extraction, Characterization, and Life Cycle Assessment of Nanosilica From Millet Husk: A Sustainable Alternative with Low Environmental Impact
Authors: Dominic C D, Midhun
Rosa, Derval dos Santos
Barbosa, Rennan Felix da Silva
Anagha, O V
Neenu, K V
Begum, P MSabura
Kumar, Aswathy V
Parameswaranpillai, Jyotishkumar
Siriwong, Chomsri
Ajithkumar, T G
Shelke, Ankita
Pasc, Andreea
Keywords: Life Cycle Assessment
Millet Husk
Nanosilica
Oxalic Acid
Issue Date: 2024
Publisher: Journal of Cleaner Production
Elsevier Ltd
Citation: Vol. 442
Abstract: Eco-friendly approaches for silica production are highly researched to respond increasing industrial demand for bio-nanofillers. Herein, nanosilica of 10–20 nm with mesoporosity was obtained through a mild oxalic acid pre-treatment of millet husk, followed by calcination at 700 °C for 2 h. Compared with commercial precipitated silica (CS) and millet husk ash (MHA) directly obtained by calcination of the husk, the pre-treated silica (MHS) had higher purity, revealed using EDX spectroscopy. Moreover, FTIR and 29Si NMR showed a higher condensation degree in MHS with 73% of Q4 siloxane bonds vs 4% in MHA. The release of the metal and organic impurities from the husk also allows to reduce the crystallinity of MHS, and to increase the specific surface area from 82 m2/g in MHA to 238 m2/g in MHS. The type II N2 adsorption-desorption isotherms of MHA and MHS indicate aggregates of non-porous silica particles. MHS also demonstrated remarkable thermal resilience. According to the LCA analysis, MHS has a 40% lower impact on global warming, a 38% lower impact on human carcinogenic toxicity, and a 38% lower impact on terrestrial acidification compared to rice husk nanosilica. This research thus addresses sustainability challenges by repurposing millet husks, which are readily available due to continuous millet cultivation, particularly in India. By reducing the ecological impact of husk disposal through burning, this study offers an economically viable technology for high-purity silica production, aligning with global efforts to combat climate change and promote sustainable practices. © 2024 Elsevier Ltd
URI: https://doi.org/10.1016/j.jclepro.2024.140924
http://gnanaganga.inflibnet.ac.in:8080/jspui/handle/123456789/15097
ISSN: 0959-6526
Appears in Collections:Journal Articles

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