Crystallization In Pcl-Based Blends and Composites

Abstract

Poly(?-caprolactone) (PCL) is known for its biodegradability, mechanical properties, processability, and compatibility with other polymers. The biodegradability of PCL mainly depends on the crystallinity and molecular weight, along with the different degradation mechanisms under different conditions. Studies on the kinetics of crystallization are important in designing suitable polymers for various applications and for obtaining desired morphology, which is of utmost importance to achieve the required properties. In this chapter, factors affecting the crystallization behavior of PCL are discussed. The change in the crystalline behavior of PCL in multiphase polymer systems such as PCL-based blends and composites is discussed. The influence of crystalline behavior on the properties of PCL is also outlined in this book chapter. © 2023 WILEY-VCH GmbH.